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5)
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Moilanen, S. B.; Potuzak, J. S.; Tan, D. S.* "Stereocontrolled synthesis of spiroketals via Ti(Oi-Pr)4-mediated kinetic spirocyclization of glycal epoxides with retention of configuration." J. Am. Chem. Soc. 2006, 128, 1792–1793.
[ Abstract | PDF | Supporting Info ]
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Highlighted in Nature
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4)
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Potuzak, J. S.; Moilanen, S. B.; Tan, D. S.* "Stereocontrolled synthesis of spiroketals via a remarkable methanol-induced kinetic spirocyclization reaction." J. Am. Chem. Soc. 2005, 127, 13796–13797.
[ Abstract | PDF | Supporting Info ]
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2)
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Moilanen, S. B.; Tan, D. S.* "Enantioselective synthesis of erythro-4-deoxyglycals as scaffolds for target- and diversity-oriented synthesis: New insights into glycal reactivity." Org. Biomol. Chem. 2005, 3, 798–803.
[ Abstract | PDF | Supporting Info ]
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Potuzak, J. S.; Tan, D. S.* "Synthesis of C1-alkyl and C1-acylglycals from glycals using a B-alkyl Suzuki–Miyaura cross coupling approach." Tetrahedron Lett. 2004, 45, 1797–1801.
[ Abstract | PDF | Supporting Info ]
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For reviews on target-oriented synthesis of spiroketals, see:
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Perron, F.; Albizati, K. F.* Chem. Rev. 1989, 89, 1617–1661.
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Boivin, T. L. B.* Tetrahedron 1987, 43, 3309–3362.
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For previous reports on diversity-oriented synthesis using thermodynamic spiroketal scaffolds, see:
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Haag, R.; Leach, A. G.; Ley, S. V.*; Nettekoven, M.; Schnaubelt, J. Synth. Commun. 2001, 31, 2965–2977.
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Kulkarni, B. A; Roth, G. P.; Lobkovsky, E.; Porco, J. A.* J. Comb. Chem. 2002, 4, 56–72.
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Barun, O.; Somer, S.; Waldmann, H.* Angew. Chem. Intl. Ed. 2004, 43, 3195–3199.
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