Publications

"Synthesis and Structure Verification of the Vaccine Adjuvant QS-7-Api. Synthetic Access to Homogeneous Quillaja saponaria Immunostimulants." Deng, K.; Adams, M. A.; Gin, D. Y. J. Am. Chem. Soc. 2008, 130 (accepted).

"Synthesis of Anti-Proliferative Cephalotaxus Esters and Their Evaluation Against Several Human Hematopoietic and Solid Tumor Cell Lines. Ester Chain Structure in the Modulation of Multi-Drug Resistance." Eckelbarger, J. D.; Wilmot, J. T.; Epperson, M. T.; Thakur, C. S.; Shum, D.; Antczak, C.; Tarassishin, L.; Djaballah, H.; Gin, D. Y. Chem. Eur. J. 2008, 14, (web early view).

"Application of an Intramolecular Dipolar Cycloaddition to an Asymmetric Synthesis of the Fully Oxygenated Tricyclic Core of the Stemofoline Alkaloids." Carra, R. J.; Epperson, M. T.; Gin, D. Y. Tetrahedron 2008, 64, 3629-3641.

"Asymmetric Synthetic Access to the Hetisine Alkaloids. Total Synthesis of (+)-Nominine" Peese, K. M.; Gin, D. Y. Chem. Eur. J. 2008, 14, 1654-1665.

"Chemical Glycosylation in the Synthesis of Glycoconjugate Antitumour Vaccines." Galoniæ, D. P.; Gin, D. Y. Nature 2007, 446, 1000-1007.

"Total Synthesis of (+)-Batzelladine A and (-)-Batzelladine D via [4+2]-Annulation of Vinyl Carbodiimides with N-Alkyl Imines." Arnold, M. A.; Day, K. A.; Durón, S. G.; Gin, D. Y. J. Am. Chem. Soc. 2006, 128, 13255-13260.

"Synthetic Studies of Complex Immunostimulants from Quillaja Saponaria. Synthesis of the Potent Clinical Immunoadjuvant QS-21Aapi." Kim, Y.-J.; Wang, P.; Navarro-Villalobos, M.; Rohde, B. D.; Derryberry, J.; Gin, D. Y. J. Am. Chem. Soc. 2006, 128, 11906-11915.

"Strain-Release Rearrangement of N-Vinyl-2-Arylaziridines. Total Synthesis of the Anti-Leukemia Alkaloid (-)-Deoxyharringtonine." Eckelbarger, J. E.; Wilmot, J. T.; Gin, D. Y. J. Am. Chem. Soc. 2006, 128, 10370-10371.

"Efficient Synthetic Access to the Hetisine C20-Diterpenoid Alkaloids. A Concise Synthesis of Nominine via Oxidoisoquinolinium-1,3-Dipolar and Dienamine-Diels-Alder Cycloadditions." Peese, K. M.; Gin, D. Y. J. Am. Chem. Soc. 2006, 128, 8734-8735.

"Highly Convergent Synthesis of C3- or C2-Symmetric Carbohydrate Macrocycles." Bodine, K. D.; Gin, D. Y.; Gin, M. S. Org. Lett. 2005, 7, 4479-4482.

"Conjugation of Selenols with Aziridine-2-Carboxylic Acid-Containing Peptides." Ide, N. D.; Galonic, D. P.; van der Donk, W. A.; Gin, D. Y. Synlett 2005, 2011-2014.

"An Enantioselective Approach to the Hetisine Alkaloids. Synthesis of the 3-Methyl-1-aza-tricyclo[5.2.1.03,8]decane Core via Intramolecular Dipolar Cycloaddition." Peese, K. M.; Gin, D. Y. Org. Lett. 2005, 7, 3323-3325.

"Sulfoxide Covalent Catalysis in Dehydrative Glycosylation. Probing the Mechanism of Hemiacetal Activation." Boebel, T. A.; Gin, D. Y. J. Org. Chem. 2005, 70, 5818-5826.

"Aziridine-2-Carboxylic Acid Containing Peptides. Application to Solution- and Solid-Phase Convergent Site-Selective Peptide Modification." Galonic, D. P.; Ide, N. D.; van der Donk, W. A.; Gin, D. Y. J. Am. Chem. Soc. 2005, 127, 7359-7369. "Research Highlights" Nature 2005, 435, 250-251.

"Diastereoselective [4+2] Annulation of Vinyl Carbodiimides with N-Alkyl Imines. Asymmetric Synthetic Access to the Batzelladine Alkaloids." Arnold, M. A.; Durón, S. G.; Gin, D. Y. J. Am. Chem. Soc. 2005, 127, 6924-6925.

"Site-Selective Conjugation of Thiols with Aziridine-2-Carboxylic Acid Containing Peptides." Galonic, D. P.; van der Donk, W. A.; Gin, D. Y. J. Am. Chem. Soc. 2004, 126, 12712-12713.

"Synthesis of the Potent Immunostimulatory Adjuvant QS-21A." Wang, P.; Kim, Y.-J.; Navarro-Villalobos, M.; Rohde, B. D.; Gin, D. Y. J. Am. Chem. Soc. 2005, 127, 3256-3257. "Research Highlights" Nature 2005, 434, 290.

"Synthesis of Readily Modifiable Cyclodextrin Analogs via Cyclodimerization of an Alkynyl-Azido Trisaccharide." Bodine, K. D.; Gin, D. Y.; Gin, M. S. J. Am. Chem. Soc. 2004, 126, 1638-1639.

"Oligosaccharide-Peptide Ligation of Glycosyl Thiolates with Dehydropeptides. Synthesis of S-Linked Mucin Glycopeptide Conjugates." Galonic, D. P.; van der Donk, W. A.; Gin, D. Y. Chem. Eur. J. 2003, 9, 5997-6006.

"Sulfoxide Covalent Catalysis. Application to Glycosidic Bond Formation." Boebel, T. A.; Gin, D. Y. Angew. Chem. Int. Ed. 2003, 42, 5874-5877.

"Dehydrative Sialylation with C2-Hemiketal Donors." Haberman, J. M.; Gin, D. Y. Org. Lett. 2003, 5, 2539-2541.

"C2-Acetamidomannosylation. Synthesis of 2-N-Acetylamino-2-Deoxy-alpha-D-Mannopyranosides with Glucal Donors." Liu, J.; Gin, D. Y. Tetrahedron Lett. 2003, 44, 4015-4018.

"Dehydrative Glycosylation with 1-Hydroxy Donors." Gin, D. Y. J. Carbohydr. Chem. 2002, 21, 645-665.

"C2-Amidoglycosylation. Scope and Mechanism of Nitrogen Transfer." Liu, J.; Gin, D. Y. J. Am. Chem. Soc. 2002, 124, 9789-9797.

"C2-Hydroxyglycosylation with Glycal Donors. Probing the Mechanism of Sulfonium-Mediated Oxygen Transfer to Glycal Enol Ethers." Honda, E.; Gin, D. Y. J. Am. Chem. Soc. 2002, 124, 7343-7352.

"Enantiospecific Synthesis of the Bridged Pyrrolizidine Core of Asparagamine A. Dipolar Cycloadditions of Azomethine Ylides Derived from the Sulfonylation of Vinylogous Amides." Epperson, M. T.; Gin, D. Y. Angew. Chem. Int. Ed. 2002, 41, 1778-1780.

"Sulfide-Mediated Dehydrative Glycosylation with 1-Hydroxy Donors." Nguyen, H. M.; Chen, Y.; Durón, S. G.; Gin, D. Y. J. Am. Chem. Soc. 2001, 123, 8766-8772.

"C(2)-Acyloxyglycosylation with Glycal Donors." Shi, L.; Kim, Y.-J.; Gin, D. Y. J. Am. Chem. Soc. 2001, 123, 6939-6940.

"Synthesis of the Trisaccharide Portion of the Immunologic Adjuvant QS-21A via Sulfonium Mediated Oxidative and Dehydrative Glycosylation." Kim, Y.-J., Gin, D. Y. Org. Lett. 2001, 3, 1801-1804.

"A New C(1)-Auxiliary for Anomeric Stereocontrol in the Synthesis of alpha-Sialyl Glycosides." Haberman, J. M.; Gin, D. Y. Org. Lett. 2001, 3, 1665-1668.

"Asymmetric Synthesis and Determination of the Absolute Configuration of the Bicyclic Guanidine Core of Batzelladine A." Durón, S. G.; Gin, D. Y. Org. Lett. 2001, 3, 1551-1554.

"Total Synthesis of (+)-Pyrenolide D." Engstrom, K. E.; Mendoza, M. R.; Navarro-Villalobos, M.; Gin, D. Y. Angew. Chem. Int. Ed. 2001, 40, 1128-1130.

"Stereoselective Synthesis of 2-Hydroxy-alpha-Mannopyranosides from Glucal Donors." Kim, J.-Y.; Di Bussolo, V.; Gin, D. Y. Org. Lett. 2001, 3, 303-306.

"Chemoselective Iterative Dehydrative Glycosylation." Nguyen, H. M.; Poole, J. L.; Gin, D. Y. Angew. Chem, Int. Ed. 2001, 40, 414-417.

Gin, D. Y. "Dehydrative Glycosylation with 1-Hydroxy Donors." in: Glycochemistry: Principles, Synthesis and Applications; Wang, P. and Bertozzi, C.R., Ed.; Marcel Dekker, Inc.: New York, NY, 2001.

"Synthesis of Glycosyl-1-Phosphates via Dehydrative Glycosylation." Garcia, B. A.; Gin, D. Y. Org. Lett. 2000, 2, 2135-2138.

"Dehydrative Glycosylation with Activated Diphenyl Sulfonium Reagents. Scope, Mode of C(1)-Hemiacetal Activation, and Detection of Reactive Glycosyl Intermediates." Garcia, B. A.; Gin, D. Y. J. Am. Chem. Soc. 2000, 122, 4269-4279.

"Acetamidoglycosylation with Glycal Donors. A One-Pot Glycosidic Coupling with Direct Stereoselective Installation of the C(2)-N-Acetylamino Functionality." Di Bussolo, V.; Liu, J.; Huffman, Jr., L. G.; Gin, D. Y. Angew. Chem. Int. Ed. 2000, 39, 204-207. "News of the Week" Chem. & Eng. News 2000, 78, 7-8.

"Direct Oxidative Glycosylations with Glycal Donors." Di Bussolo, V.; Kim, Y.-J.; Gin, D. Y. J. Am. Chem. Soc. 1998, 120, 13515-13516.

"Direct Glycosylations with 1-Hydroxy Glycosyl Donors Using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide." Garcia, B. A.; Poole, J. L.; Gin, D. Y. J. Am. Chem. Soc. 1997, 119, 7597-7598.

Site Map \| Index	Legal Disclaimer \| Privacy Practices \| Public Notices

©2008 Memorial Sloan-Kettering Cancer Center. 212-639-2000 1275 York Avenue New York, NY 10065.	PublicAffairs@mskcc.org